Chemistry

Construction and Industrial Materials Questions

Chapter: Everyday Materials and Their Chemistry | Total Available: 27 Real Questions

Question 1 of 10 Authentic UPSC NDA Question

 Refining of petroleum is carried out usingwhich one of the following techniques?

Step-by-Step Logic & Solution

Correct Answer

✓ Option (b) is correct. Fractional distillation effectively separates crude petroleum into its components based on boiling points.

📖 Governing Law / Core Concept

The refining of petroleum is governed by the principle of fractional distillation, which relies on the different boiling points of hydrocarbons.

🧪 Step-by-Step Breakdown

Crude oil is a complex mixture of hydrocarbons. Through fractional distillation, these hydrocarbons are separated in a distillation column, where:

\[ \text{Fractional Distillation} \] \

The distillation process correlates with the boiling points of the compounds:

Common ranges include:
  • Petrol: 40 - 100 °C
  • Kerosene: 150 - 250 °C
  • Diesel: 250 - 350 °C
  • LPG: below 40 °C

🔍 Option Analysis

  • A: Evaporation - Not suitable as it does not separate based on boiling point.
  • C: Separating funnel - Used for separating immiscible liquids, not applicable here.
  • D: Sublimation - A process for solids that change directly to gas; irrelevant for crude oil.

⚡ Mnemonic / Speed-Run

Remember: "F" for Fractional distillation is for Fluid separation of hydrocarbons by Flowing boiling points.

6. Visual Suggestion

6. Visual Suggestion

A flowchart illustrating the fractional distillation process, including input of crude oil, separation into different fractions at various boiling points, and collection of desired products.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter 5 (States of Matter) and Chapter 12 (Organic Chemistry).

Question 2 of 10 Authentic UPSC NDA Question

Which one of the following is NOT present in cement?

Step-by-Step Logic & Solution

Correct Answer

✓ Option C is correct. The compound 4CaO·SiO2 is not a standard component of cement.

📖 Governing Law / Core Concept

Cement typically consists of calcium silicates and aluminates which are critical for its physical properties and setting characteristics.

🧪 Step-by-Step Breakdown

Cement composition includes:

  • 2CaO·SiO2 (Belite) - contributes to strength.
  • 3CaO·SiO2 (Alite) - predominant in modern cements.
  • 3CaO·Al2O3 - enhances early strength.
  • 4CaO·SiO2 - is absent in conventional cement.

Thus, the correct identification of non-standard material is:

4CaO·SiO2 is simply not utilized in common cement mixtures.

🔍 Option Analysis

  • Option A: 2CaO·SiO2 is present as Belite.
  • Option B: 3CaO·SiO2 is the main compound known as Alite.
  • Option D: 3CaO·Al2O3 serves early strength development.

⚡ Mnemonic / Speed-Run

Remember: For cement, prioritize 2CaO·SiO2, 3CaO·SiO2, & 3CaO·Al2O3; 4CaO·SiO2 is the outlier.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter on Cement and Concrete Technology.

Question 3 of 10 Authentic UPSC NDA Question

Which one of the following is not used raw material in the manufacture of glass

Step-by-Step Logic & Solution

Correct Answer

✓ Option D is correct. Gypsum is not a raw material in glass manufacturing.

📖 Governing Law / Core Concept

Glass is primarily made from silicate materials through a melting process involving silica (SiO₂), soda (Na₂CO₃), and alumina (Al₂O₃). Gypsum (CaSO₄·2H₂O) is mainly used in the production of cement and mortar.

🧪 Step-by-Step Breakdown

In the glass manufacturing process, the commonly used raw materials are:

  • Soda (sodium carbonate) helps reduce the melting temperature.
  • Alumina enhances the durability of the glass.
  • Borax (sodium borate) can be used to improve glass clarity and strength.
  • Gypsum is not utilized in this process.

The relevant chemical reaction can be summarized as:

\[ \text{Silica} + \text{Soda} + \text{Alumina} \rightarrow \text{Glass} \]

🔍 Option Analysis

Gypsum (Option D) is used in constructing cement, while:

  • Soda (Option A): Used for reducing melting point.
  • Alumina (Option B): Improves quality and stability.
  • Borax (Option C): Enhances glass characteristics.

⚡ Mnemonic / Speed-Run

Remember the key raw materials with the mnemonic: "SAB G" (Soda, Alumina, Borax = Glass), contrasting with Gypsum.

6. Visual Suggestion

6. Visual Suggestion

A flowchart illustrating the glass production process, highlighting inputs (Silica, Soda, Alumina) and the resulting glass product, with Gypsum distinctly noted as not included.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter on General Principles and Processes of Isolation of Elements.

Question 4 of 10 Authentic UPSC NDA Question

Solder is an alloy of

Step-by-Step Logic & Solution

Correct Answer

✓ Option (c) is correct. Solder is primarily composed of lead (Pb) and tin (Sn).

📖 Governing Law / Core Concept

Soldering involves an alloy of lead and tin, which melts at a lower temperature (around 180-190 °C) compared to pure metals, allowing for effective joining without damaging components.

🧪 Step-by-Step Breakdown

Solder primarily consists of:

  • Lead (Pb): a soft, malleable metal.
  • Tin (Sn): a metal that provides strength and corrosion resistance.

The typical composition is:

  • 60% Tin (Sn) to 40% Lead (Pb).
  • Other proportions can include up to 90% Sn and 10% Pb.

These alloys make solder suitable for electronic and plumbing applications.

🔍 Option Analysis

Other options are incorrect because:

  • A: Copper (Cu) and tin (Sn) form bronze, not solder.
  • B: Iron (Fe) and zinc (Zn) create galvanization, not solder.
  • D: Silver (Ag) and zinc (Zn) are not used in soldering.

⚡ Mnemonic / Speed-Run

Remember "Lead and Tin Got Soldered In" to recall that solder is made from lead (Pb) and tin (Sn).

6. Visual Suggestion

6. Visual Suggestion

A table comparing the properties of solder alloys, including melting points and typical applications, would enhance understanding.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter on Alloys and their Applications.

Question 5 of 10 Authentic UPSC NDA Question

Which one of the following statements about the cleansing action of soap is not true?

Step-by-Step Logic & Solution

Correct Answer

✓ Option (c) is correct. Soaps are sodium or potassium salts, not ammonium salts.

📖 Governing Law / Core Concept

Soaps are formed as sodium or potassium salts of long-chain carboxylic acids, exhibiting amphipathic properties, meaning they possess both hydrophilic (polar) and hydrophobic (non-polar) regions.

🧪 Step-by-Step Breakdown

Soap molecules consist of a long hydrocarbon chain (non-polar) and a carboxylate group (polar), allowing them to interact with both water and grease. When soap is added to water, the molecules arrange themselves into spherical structures called micelles:

\[\text{Micelle Structure: Oil and dirt trapped inside, surrounded by soap molecules}\]

A micelle forms when the polar heads face outward towards the water, while the non-polar tails face inward, encapsulating dirt or oil.

🔍 Option Analysis

Option A: True - The oil and dirt get collected in the center of the micelle.

Option B: True - Soap micelles scatter light due to their size.

Option D: True - Soap reacts with calcium (Ca) and magnesium (Mg) ions in hard water to form insoluble precipitates.

⚡ Mnemonic / Speed-Run

Mneumonic for Soap Formation: "Sodium Carbs Spread, Not Ammonium!"

6. Visual Suggestion

6. Visual Suggestion

A diagram of soap micelle formation, showing polar heads interacting with water and non-polar tails trapping grease, illustrating how dirt is encapsulated.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter 5 (States of Matter and Thermodynamics).

Question 6 of 10 Authentic UPSC NDA Question

Common salt (NaCl) is not used as a raw material for preparation of which one of the following compounds?

Step-by-Step Logic & Solution

Correct Answer

✓ Option (C) is correct. Common salt (NaCl) is not used in the manufacture of plaster of Paris.

📖 Governing Law / Core Concept

The preparation of plaster of Paris involves gypsum (calcium sulfate dihydrate, \( \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \)), not sodium chloride (NaCl).

🧪 Step-by-Step Breakdown

Plaster of Paris is produced by heating gypsum:

\[ \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \xrightarrow{\Delta} \text{CaSO}_4 \cdot \frac{1}{2}\text{H}_2\text{O} + 1.5\text{H}_2\text{O} \]

In comparison:

  • Option A: Bleaching Powder is made from chlorine and slaked lime.
  • \[ \text{Ca(OH)}_2 + \text{Cl}_2 \rightarrow \text{Ca(OCl)}_2 + \text{HCl} \]
  • Option B: Baking Soda is produced from sodium carbonate and carbon dioxide.
  • \[ \text{Na}_2\text{CO}_3 + \text{CO}_2 + \text{H}_2\text{O} \rightarrow 2 \text{NaHCO}_3 \]
  • Option D: Washing Soda is made by the reaction of sodium carbonate sesquihydrate with water.
  • \[ \text{Na}_2\text{CO}_3 + 10 \text{H}_2\text{O} \rightarrow \text{Na}_2\text{CO}_3 \cdot 10\text{H}_2\text{O} \]

🔍 Option Analysis

While NaCl is used in making washing soda, baking soda, and bleaching powder, it is not a component in the synthesis of plaster of Paris, which exclusively requires gypsum.

⚡ Mnemonic / Speed-Run

Remember: "Sodium is for soda, but gypsum is for plaster."

6. Visual Suggestion

6. Visual Suggestion

Diagram showing the thermal decomposition of gypsum to plaster of Paris, with labels for reactants, products, and reaction conditions.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter 2 (Structure of Atom and Periodicity in Properties).

Question 7 of 10 Authentic UPSC NDA Question

Which one of the following is NOT a synthetic detergent ?

Step-by-Step Logic & Solution

Correct Answer

✓ Option C is correct. It represents a long-chain fatty acid salt, which is a natural soap, not a synthetic detergent.

📖 Governing Law / Core Concept

Synthetic detergents are artificial cleaning agents with surfactant properties, primarily derived from petrochemicals. They can be divided into anionic, cationic, and non-ionic detergents.

🧪 Step-by-Step Breakdown

Analyzing the given options:

  • Option A: CH₃(CH₂)₁₀CH₂OSO₃⁻ Na⁺ is an anionic synthetic detergent.
  • Option B: [CH₃(CH₂)₁₅N(CH₃)₃]⁺ Br⁻ is a cationic synthetic detergent.
  • Option C: CH₃(CH₂)₁₆COO⁻ Na⁺ is a natural soap formed from a fatty acid and sodium, hence not a synthetic detergent.
  • Option D: CH₃(CH₂)₁₆COO(CH₂CH₂O)ₙCH₂CH₂OH is a non-ionic synthetic detergent.

🔍 Option Analysis

Option A and B are synthetic detergents with surfactant properties. Option C is a natural product (soap), while Option D is a synthetic non-ionic detergent.

⚡ Mnemonic / Speed-Run

Remember: "Synthetic = Petrochemical", while "Soap = Fatty Acid + Na".

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter on Surface Chemistry.

Question 8 of 10 Authentic UPSC NDA Question

Which one of the following is an example of a clean fuel ?

Step-by-Step Logic & Solution

Correct Answer

✓ Option [b] is correct. Propane is a clean fuel with lower emissions compared to other options.

📖 Governing Law / Core Concept

Clean fuels are characterized by lower carbon emissions and pollutants during combustion, contributing to a reduction in environmental and health impacts.

🧪 Step-by-Step Breakdown

  • Coke: A carbon-rich fuel produced from coal, resulting in high CO2 emissions.
  • Propane: A hydrocarbon (C3H8) with clean-burning properties, emitting only CO2 and water vapor.
  • Petrol: Produces CO2, NOx, and particulate matter, making it less clean than propane.
  • Wax: While it burns cleanly, it isn’t typically classified as a fuel for combustion engines or heating.

🔍 Option Analysis

A: Coke contributes significantly to air pollution.
B: Propane is indeed a clean fuel option.
C: Petrol has substantial pollutants compared to propane.
D: Wax is not commonly used as a fuel source.

⚡ Mnemonic / Speed-Run

Remember: Propane = Cleanest fuel. (Propane emits the fewest pollutants.)

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against environmental science principles regarding clean fuels and emissions.

Question 9 of 10 Authentic UPSC NDA Question

Which one of the following is used as a binder in paints ?

Step-by-Step Logic & Solution

Correct Answer

✓ Option D is correct. Silicones are commonly used as binders in paints due to their excellent adhesion and flexible properties.

📖 Governing Law / Core Concept

In paint formulations, binders are crucial as they provide adhesion, durability, and finish to the paint film. Silicones, particularly in the form of polysiloxanes, are known for their unique properties, which include resistance to temperature extremes and moisture.

🧪 Step-by-Step Breakdown

  • Silicone Binders: Composed of silicon-oxygen frameworks, these materials provide superior elasticity and thermal stability.
  • Adhesion: Silicone binders enhance the adhesion of paint to various surfaces, ensuring a long-lasting finish.
  • Flexibility: Their flexibility allows paints to withstand cracking and peeling.

🔍 Option Analysis

  • A: Titanium dioxide - Primarily a white pigment, not a binder.
  • B: Novolac - A phenolic resin used in specific coatings but not in general paints.
  • C: Phthalocyanine - A pigment known for color, not as a binder.

⚡ Mnemonic / Speed-Run

Remember: "Silicones Stick!" to recall that silicones are effective binders, enhancing adhesion and resilience in paints.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against standard chemistry materials covering polymer science and paint technology.

Question 10 of 10 Authentic UPSC NDA Question

Which one of the following statements about glass is not correct?

Step-by-Step Logic & Solution

Correct Answer

✓ Option C is correct. Soda glass is not harder than Pyrex glass.

📖 Governing Law / Core Concept

Glass is an amorphous solid that lacks a defined crystalline structure. The properties of different types of glass, such as Soda glass and Pyrex glass, are governed by their chemical composition and thermal treatment.

🧪 Step-by-Step Breakdown

Comparison of Glass Types:

  • Soda glass is made primarily from silica, soda, and limestone and is commonly used for everyday products.
  • Pyrex glass contains boron trioxide, which enhances thermal resistance and strength.

Therefore, Pyrex glass is harder and more resistant to thermal shock compared to regular Soda glass, making Option C incorrect.

🔍 Option Analysis

  • A: This statement is often used to describe glass's characteristics but is misleading since it behaves more like a solid than a liquid over a practical time scale.
  • B: Correct, as glass transitions from solid to liquid without a distinct melting point.
  • D: Correct, as boron improves the thermal properties of Pyrex glass.

⚡ Mnemonic / Speed-Run

Remember: Pyrex is for heat resistance, whereas soda glass is for everyday use. Use "Pyrex = Performance" to recall its superiority in thermal properties.

6. Visual Suggestion

6. Visual Suggestion

A comparative diagram illustrating the molecular structure of Soda glass versus Pyrex glass, highlighting differences in composition and thermal properties would be helpful.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against standard chemistry references regarding glass properties and compositions.

Today's UPSC Current Affairs

Padma Bhushan Call Deepens India Election Commission Row - streamlinefeed.co.ke

Read Today's Digest